Three-dimensional porous activated carbon derived from loofah sponge biomass for supercapacitor applications

被引:272
作者
Su, Xiao-Li [1 ]
Chen, Jing-Ran [1 ]
Zheng, Guang-Ping [2 ]
Yang, Jing-He [3 ]
Guan, Xin-Xin [1 ,4 ]
Liu, Pu [1 ]
Zheng, Xiu-Cheng [1 ,4 ]
机构
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Hong Kong Polytech Univ, Dept Mech Engn, Hong Kong, Hong Kong, Peoples R China
[3] Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China
[4] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
Loofah sponge; Activated carbon tube; Hierarchical porous structure; Electrochemical behaviors; Supercapacitors; PERFORMANCE ELECTRODE MATERIALS; MICROPOROUS CARBON; NITROGEN; WASTE; LAYER; POROSITY; POLYMER;
D O I
10.1016/j.apsusc.2017.11.249
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biomass carbon source is generally cheap, environmentally friendly and readily available in high quality and quantity. In this work, a series of loofah sponge-derived activated carbon (SAC-x) with hierarchical porous structures are prepared by KOH chemical activation and used as electrode materials for supercapacitors. The pore size can be easily controllable by changing the dosage of KOH. The optimized material (SAC-4) exhibits a high specific capacitance of 309.6 F g(-1) at 1 A g(-1) in the three-electrode system using 6 M KOH electrolyte. More importantly, the as-assembled symmetric supercapacitor based on SAC-4 exhibits a high energy density of 16.1 Wh kg(-1) at a power density of 160.0 W kg(-1) using 1 M Na2SO4 electrolyte. These remarkable results demonstrate the exciting commercial potential of SAC-x for high-performance supercapacitor applications due to their high specific surface area, appropriately porous structure, and the trace heteroatom (O and N) functionalities. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:327 / 336
页数:10
相关论文
共 46 条
[1]   Polypyrrole/carbon nanotube supercapacitors: Technological advances and challenges [J].
Afzal, Adeel ;
Abuilaiwi, Faraj A. ;
Habib, Amir ;
Awais, Muhammad ;
Waje, Samaila B. ;
Atieh, Muataz A. .
JOURNAL OF POWER SOURCES, 2017, 352 :174-186
[2]   Fallen-leaf-derived microporous pyropolymers for supercapacitors [J].
An, Hong Joo ;
Kim, Na Rae ;
Song, Min Yeong ;
Yun, Young Soo ;
Jin, Hyoung-Joon .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 45 :223-228
[3]   Facile synthesis of rod-like manganese molybdate crystallines with two-dimentional nanoflakes for supercapacitor application [J].
Cao, Huili ;
Wu, Nannan ;
Liu, Yuzhen ;
Wang, Shenyu ;
Du, Wenjing ;
Liu, Jiurong .
ELECTROCHIMICA ACTA, 2017, 225 :605-613
[4]   Three-dimensional scaffolding framework of porous carbon nanosheets derived from plant wastes for high-performance supercapacitors [J].
Chen, Chong ;
Yu, Dengfeng ;
Zhao, Gongyuan ;
Du, Baosheng ;
Tang, Wei ;
Sun, Lei ;
Sun, Ye ;
Besenbacher, Flemming ;
Yu, Miao .
NANO ENERGY, 2016, 27 :377-389
[5]   Cotton fabric derived hierarchically porous carbon and nitrogen doping for sustainable capacitor electrode [J].
Chen, Long ;
Ji, Tuo ;
Mu, Liwen ;
Zhu, Jiahua .
CARBON, 2017, 111 :839-848
[6]   Hierarchically porous carbon by activation of shiitake mushroom for capacitive energy storage [J].
Cheng, Ping ;
Gao, Shuangyan ;
Zang, Peiyu ;
Yang, Xiaofan ;
Bai, Yonglong ;
Xu, Hua ;
Liu, Zonghuai ;
Lei, Zhibin .
CARBON, 2015, 93 :315-324
[7]   Unique elastic N-doped carbon nanofibrous microspheres with hierarchical porosity derived from renewable chitin for high rate supercapacitors [J].
Duan, Bo ;
Gao, Xiang ;
Yao, Xu ;
Fang, Yan ;
Huang, Liang ;
Zhou, Jun ;
Zhang, Lina .
NANO ENERGY, 2016, 27 :482-491
[8]   Enhanced pseudocapacitive performance of electroactive p-type conductive polymer in the presence of 1-octadecyl-3-methylimidazolium bromide [J].
Ehsani, A. ;
Kowsari, E. ;
Najafi, M. Dashti ;
Safari, R. ;
Shiri, H. Mohammad .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 503 :10-16
[9]   Microporous carbon derived from acacia gum with tuned porosity for high-performance electrochemical capacitors [J].
Fan, Yang ;
Liu, Peifang ;
Zhu, Bing ;
Chen, Shufang ;
Yao, Kaili ;
Han, Ran .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (18) :6188-6196
[10]   Hierarchical structured carbon derived from bagasse wastes: A simple and efficient synthesis route and its improved electrochemical properties for high-performance supercapacitors [J].
Feng, Haobin ;
Hu, Hang ;
Dong, Hanwu ;
Xiao, Yong ;
Cai, Yijin ;
Lei, Bingfu ;
Liu, Yingliang ;
Zheng, Mingtao .
JOURNAL OF POWER SOURCES, 2016, 302 :164-173