Study of degradation of p-toluic acid by photo-oxidation, peroxidation, photo-peroxidation and photo-fenton processes

被引:2
作者
Mandavgane, Susmita A. [1 ]
机构
[1] DRB Sindhu Mahavidyalaya, Dept Chem, Nagpur 440017, Maharashtra, India
关键词
p-Toluic acid; Photo-oxidation; Peroxidation; Photo-peroxidation; Fenton processes; First order dynamics; OXIDATION; PHARMACEUTICALS; REMOVAL; DESTRUCTION; WATER;
D O I
10.1016/j.matpr.2020.05.478
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
p-Toluic acid is a major content of terephthalic acid wastewater and is a cause of secondary water pollution. p-Toluic acid in aqueous solution was degraded by using photo-fenton, photo-peroxidation, photo-oxidation and peroxidation processes. A low-pressure mercury vapour lamp was taken in combination with different oxidants to degrade p-toluic acid in this study. Substrate concentration was fixed by utilizing a UV-Visible spectrophotometer. The results indicated that photo-fenton process achieved degradation rate due to synergistic effect between UV and Fe2+/H2O2. The degradation rate follow the sequence: photofenton (UV/ Fe2+/H2O2) > photo-peroxidation (UV/H2O2) > photo-oxidation (UV) > peroxidation (H2O2). The photodegradation processes were adhered to first order dynamics. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1213 / 1216
页数:4
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