Cucurbituril as a new "host" of organic molecules in inclusion complexes

被引：17

作者：

Chernikova, E. Yu ^{[1
]}

Fedorov, Yu V. ^{[1
]}

Fedorova, O. A. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 07期

关键词：

supramolecular chemistry; cucurbituril; host-guest complexes; intermolecular interactions; organic cations; photochemical reactions; CHARGE-TRANSFER COMPLEX; STEREOSELECTIVE PHOTODIMERIZATION; POLYMER NANOCAPSULES; REVERSIBLE FORMATION; GUEST COMPLEXATION; CINNAMIC-ACIDS; BINDING MODES; DERIVATIVES; HOMOLOGS; MACHINE;

D O I：

10.1007/s11172-012-0180-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The latest data concerning the study of inclusion complexes based on cucurbiturils as a new class of molecular hosts are generalized in the review. The methods of synthesis, the structure, and physical and chemical properties of cucurbiturils are considered. Special attention is given to the discussion of the principles of construction of supramolecular complexes. The factors affecting stability, composition, and structure of inclusion complexes are considered. The potential applications of cucurbituril as molecular containers for a number of photochemical reactions are given. Advantages of using this class of compounds in comparison with other known cavitands are presented.

引用

页码：1363 / 1390

页数：28

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