Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions

被引:21
|
作者
Tian, Aixiang [1 ]
Lin, Xiaoling [1 ]
Ying, Jun [1 ]
Zhang, Juwen [1 ]
Lin, Hongyan [1 ]
Liu, Guocheng [1 ]
Zhao, Dan [1 ]
Li, Na [1 ]
Wang, Xiuli [1 ]
机构
[1] Bohai Univ, Dept Chem, Jinzhou 121000, Peoples R China
基金
中国国家自然科学基金;
关键词
POLYOXOMETALATE; CRYSTAL; COORDINATION; CONSTRUCTION; COMPLEXES; FRAMEWORK; CLUSTERS; SINGLE; LIGAND;
D O I
10.1039/c3dt50800e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Four Ag-I ions are linked by four 5-phenyl-1H-tetrazole (Hptz) units to form a molecular crown [Ag-4(ptz)(4)] as a structural analogue of calix[4]arene, which are further supported by Keggin anions to build a 2D layer containing two kinds of cycles, [Ag-8-(ptz)(4)((HPW2W10O40)-W-V-O-VI)]center dot 2H(2)O (1).
引用
收藏
页码:9809 / 9812
页数:4
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