Synthesis and Characterization of A Novel Star-shaped Polymers with Biological Compatibility via Ring-opening Polymerization and Atom Transfer Radical Polymerization

被引：0
|
作者：
Zhou, Shibiao [1 ]
Xiao, Anguo [1 ]
Chen, Yuandao [1 ]
Zhuang, Yongbing [1 ]
Wang, Yun [1 ]
机构：
[1] Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China
来源：
PROGRESS IN MATERIALS AND PROCESSES, PTS 1-3 | 2013年 / 602-604卷
关键词：
ROP; ATRP; Star-shaped polymer; PCL; POEOMA; COPOLYMERS; MOLECULES;
D O I：
10.4028/www.scientific.net/AMR.602-604.727
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Hydroxyl functional hyperbranched polyester initiators initiated the ring-opening polymerization(ROP) of epsilon-caprolactone (CL) and the star-shaped polymer with PCL arms using hyperbranched polyester as nuclear was produced. Then, the bromide of star-shaped polymer, initiated the atom transfer radical polymerization (ATRP) of oligo(ethylene oxide) methacrylate (OEOMA) and the star-shaped polymer containing the arms of PCL-b-POEOMA was synthesized,and the characterization of polymer structure was investigated by NMR.
引用
收藏
页码：727 / 731
页数：5
相关论文
共 50 条
  • [41] A Facile, Controlled Synthesis of Soluble Star Polymers Containing a Sugar Residue by Ring-Opening Metathesis Polymerization (ROMP)
    Otani, Hisaki
    Fujita, Sakiko
    Watanabe, Yu
    Fujiki, Michiya
    Nomura, Kotohiro
    OLEFIN METATHESIS, 2010, 293 : 53 - 57
  • [42] Atom transfer radical polymerization of an epoxide-containing monomer, 4-vinylphenyloxirane, employing low concentration of catalyst: synthesis of linear and star-shaped macromolecules
    McLeod, David C.
    Tsarevsky, Nicolay V.
    POLYMER INTERNATIONAL, 2014, 63 (05) : 868 - 875
  • [43] Synthesis and characterization of poly(ethylene glycol) bottlebrush networks via ring-opening metathesis polymerization
    Clarke, Brandon R.
    Tew, Gregory N.
    JOURNAL OF POLYMER SCIENCE, 2022, 60 (09) : 1501 - 1510
  • [44] Combination of template polymerization and atom transfer radical polymerization: Strategy for synthesis of specifically structural polymers
    Saito, Reiko
    POLYMER, 2008, 49 (11) : 2625 - 2631
  • [45] Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers
    Xia, Yan
    Kornfield, Julia A.
    Grubbs, Robert H.
    MACROMOLECULES, 2009, 42 (11) : 3761 - 3766
  • [46] Synthesis and Characterization of Clay Dispersed Polystyrene Nanocomposite via Atom Transfer Radical Polymerization
    Roghani-Mamagani, Hossein
    Haddadi-Asl, Vahid
    Najafi, Mohammad
    Salami-Kalajahi, Mehdi
    POLYMER COMPOSITES, 2010, 31 (11) : 1829 - 1837
  • [47] Synthesis of Triphenyl Phosphine Oxide-Containing Polymers via Atom Transfer Radical Polymerization
    Turel, Betul
    Karatas, Sevim
    Gungor, Atilla
    Serhatli, I. Ersin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 128 (01) : 888 - 898
  • [48] Ring-Opening Metathesis Polymerization of 18-e Cobalt(I)-Containing Norbornene and Application as Heterogeneous Macromolecular Catalyst in Atom Transfer Radical Polymerization
    Yan, Yi
    Zhang, Jiuyang
    Wilbon, Perry
    Qiao, Yali
    Tang, Chuanbing
    MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (21) : 1840 - 1845
  • [49] Amphiphilic diblock star polymer catalysts via atom transfer radical polymerization
    Dichtel, William R.
    Baek, Kyung-Youl
    Frechet, Jean M. J.
    Rietveld, Ivo B.
    Vinogradov, Sergei A.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (17) : 4939 - 4951
  • [50] Grafting of polymers via ring-opening polymerization for electrochemical assay of alkaline phosphatase activity
    Zhu, Xin
    Wang, Wenbin
    Lu, Jing
    Hao, Lulu
    Yang, Huaixia
    Liu, Yanju
    Si, Fuchun
    Kong, Jinming
    ANALYTICA CHIMICA ACTA, 2021, 1185
12345