Synthesis and Characterization of A Novel Star-shaped Polymers with Biological Compatibility via Ring-opening Polymerization and Atom Transfer Radical Polymerization

被引：0
|
作者：
Zhou, Shibiao [1 ]
Xiao, Anguo [1 ]
Chen, Yuandao [1 ]
Zhuang, Yongbing [1 ]
Wang, Yun [1 ]
机构：
[1] Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China
来源：
PROGRESS IN MATERIALS AND PROCESSES, PTS 1-3 | 2013年 / 602-604卷
关键词：
ROP; ATRP; Star-shaped polymer; PCL; POEOMA; COPOLYMERS; MOLECULES;
D O I：
10.4028/www.scientific.net/AMR.602-604.727
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Hydroxyl functional hyperbranched polyester initiators initiated the ring-opening polymerization(ROP) of epsilon-caprolactone (CL) and the star-shaped polymer with PCL arms using hyperbranched polyester as nuclear was produced. Then, the bromide of star-shaped polymer, initiated the atom transfer radical polymerization (ATRP) of oligo(ethylene oxide) methacrylate (OEOMA) and the star-shaped polymer containing the arms of PCL-b-POEOMA was synthesized,and the characterization of polymer structure was investigated by NMR.
引用
收藏
页码：727 / 731
页数：5
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