Grafted Crystalline Poly-Perfluoroacrylate Structures for Superhydrophobic and Oleophobic Functional Coatings

被引：73
作者：
Coclite, Anna Maria [1 ]
Shi, Yujun [2 ]
Gleason, Karen K. [1 ]
机构：
[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
[2] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源：
ADVANCED MATERIALS | 2012年 / 24卷 / 33期
关键词：
fiber texture; iCVD; grafting; oleophobicity; perfluorinated coatings; superhydrophobicity; CHEMICAL-VAPOR-DEPOSITION; ACRYLATE) THIN-FILMS; LOW SURFACE-ENERGY; COPOLYMERS; MONOLAYERS; FABRICS; ROUTES; WATER; ICVD;
D O I：
10.1002/adma.201200682
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This report describes the preparation of superhydrophobic and oleophobic sur faces by grafting of poly(perfluorodecylacrylate) chains with initiated chemical vapor deposition on silicon substrates. The grafting enhances the formation of a semicrystalline phase. The crystalline structures reduce the polymer chain mobility, resulting in nonwetting surfaces with both water and mineral oil. On the contrary, the same contacting liquid easily wets the amorphous ungrafted polymer.
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收藏
页码：4534 / 4539
页数：6
相关论文
共 26 条
[1]  
Ameduri B., 2004, Well Architectured Fluoropolymers: Synthesis, Properties, and Applications
[2]   Engineering low surface energy polymers through molecular design: synthetic routes to fluorinated polystyrene-based block copolymers [J].
Andruzzi, L ;
Chiellini, E ;
Galli, G ;
Li, XF ;
Kang, SH ;
Ober, CK .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (06) :1684-1692
[3]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[4]   Fabrics with Tunable Oleophobicity [J].
Choi, Wonjae ;
Tuteja, Anish ;
Chhatre, Shreerang ;
Mabry, Joseph M. ;
Cohen, Robert E. ;
McKinley, Gareth H. .
ADVANCED MATERIALS, 2009, 21 (21) :2190-+
[5]   Controlling the Degree of Crystallinity and Preferred Crystallographic Orientation in Poly-Perfluorodecylacrylate Thin Films by Initiated Chemical Vapor Deposition [J].
Coclite, Anna Maria ;
Shi, Yujun ;
Gleason, Karen K. .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (10) :2167-2176
[6]   Ultralow surface energy plasma polymer films [J].
Coulson, SR ;
Woodward, IS ;
Badyal, JPS ;
Brewer, SA ;
Willis, C .
CHEMISTRY OF MATERIALS, 2000, 12 (07) :2031-2038
[7]   Structure of fluorinated side-chain smectic copolymers:: Role of the copolymerization statistics [J].
de Crevoisier, G ;
Fabre, P ;
Leibler, L ;
Tencé-Girault, S ;
Corpart, JM .
MACROMOLECULES, 2002, 35 (10) :3880-3888
[8]   Initiated chemical vapor deposition of poly(1H,1H,2H,2H-perfluorodecyl acrylate) thin films [J].
Gupta, Malancha ;
Gleason, Karen K. .
LANGMUIR, 2006, 22 (24) :10047-10052
[9]   Molecular aggregation structure and surface properties of poly(fluoroalkyl acrylate) thin films [J].
Honda, K ;
Morita, M ;
Otsuka, H ;
Takahara, A .
MACROMOLECULES, 2005, 38 (13) :5699-5705
[10]  
Iacono ST, 2010, J MATER CHEM, V20, P2979, DOI [10.1039/b924337b, 10.1039/B924337B]
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