σ-Bond Metathesis: A 30-Year Retrospective

被引：226
作者：
Waterman, Rory [1 ]
机构：
[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 24期
基金：
美国国家科学基金会;
关键词：
C-H BONDS; ZIRCONIUM-MEDIATED FUNCTIONALIZATION; INSERTION REACTIONS; TERMINAL ALKYNES; SI-H; OLEFIN POLYMERIZATION; ENHANCED REACTIVITY; CATALYTIC HYDROMETHYLATION; REDUCTIVE ELIMINATION; HYDRIDE DERIVATIVES;
D O I：
10.1021/om400760k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A review of sigma-bond metathesis is presented using Watson's 1983 observation of degenerative methyl ligand exchange at metallocene compounds as a starting point. This review has two major parts. The first presents identifying features and reactivity characteristics of this pivotal mechanistic step for high oxidation state metals, which are given with some historical context, though not in historical order for clarity of discussion. The second part presents several selected examples of the exploits of this transformation with a particular focus on catalytic bond forming reactions.
引用
收藏
页码：7249 / 7263
页数：15
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