Mg2SiO4 as a novel thermal barrier coating material for gas turbine applications

被引:41
作者
Chen, Si [1 ]
Zhou, Xin [1 ,2 ]
Song, Wenjia [2 ]
Sun, Junbin [1 ]
Zhang, Hao [1 ]
Jiang, Jianing [1 ]
Deng, Longhui [1 ]
Dong, Shujuan [1 ]
Cao, Xueqiang [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
[2] Ludwig Maximilians Univ LMU Munich, Dept Earth & Environm Sci, Theresienstr 41-3, D-80333 Munich, Germany
基金
中国国家自然科学基金;
关键词
Thermal barrier coating (TBC); Mg2SiO4; Plasma spraying; Thermal cycling behavior; MECHANICAL-PROPERTIES; BEHAVIOR; MICROSTRUCTURE; PERFORMANCE; ZIRCONATE; KINETICS; LA2ZR2O7; SCIENCE; STRESS; OXIDES;
D O I
10.1016/j.jeurceramsoc.2019.02.016
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Forsterite-type Mg2SiO4 was investigated systematically for thermal barrier coating (TBC) applications. Results showed that Mg2SiO4 synthesized by solid-state reaction possessed the good phase stability up to 1573 K. The thermal conductivity of Mg2SiO4 at 1273 K was lower (similar to)20% than that of yttria stabilized zirconia (8YSZ). Mg2SiO4 also presented moderate thermal expansion coefficients, which increased from 8.6 x 10(-6) K-1 to 11.3 x 10(-6) K-1 (473(similar to)623 K). Mechanical properties including hardness, fracture toughness, and Young's modulus of Mg2SiO4 were comparable to those of BYSZ. The sintering results indicated a promising low-sintering activity of Mg2SiO4. Mg2SiO4 samples were subjected to water quenching test at 1573 K and showed a superior thermal shock resistance compared to 8YSZ. Mg2SiO4 coating with stoichiometric composition was produced by atmospheric plasma spraying. The thermal cycling test result showed that Mg2SiO4 coating had a lifetime more than 830 cycles at 1273 K, which is desirable for TBC applications.
引用
收藏
页码:2397 / 2408
页数:12
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