Catalytic enantioselective Amadori-Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones

被引：38

作者：

Frongia, Angelo ^{[1
]}

Secci, Francesco ^{[1
]}

Capitta, Francesca ^{[1
]}

Piras, Pier Paolo ^{[1
]}

Sanna, Maria Luisa ^{[1
]}

机构：

[1] Univ Cagliari, Dipartimento Sci Chim & Geol, I-09042 Cagliari, Italy

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 78期

关键词：

AMINO-ACID; AMINATION; PROTONATION; ALDEHYDES; IMINOKETONES; LACTOSAMINE; HYDRATION; DIIMINES; ESTERS;

D O I：

10.1039/c3cc45278f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel synthesis of optically active alpha-arylamino ketones through an organocatalytic enantioselective Amadori-Heyns rearrangement is described.

引用

页码：8812 / 8814

页数：3

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