(N, N-Diethyldithiocarbamato)[tris(3,5-dimethylpyrazol-1-yl)hydroborato]copper(II): a new copper(II) dithiocarbamate compound with the classic TpMe2 scorpionate

被引：3

作者：

Canada, Louise Marie C. ^{[1
]}

Yap, Glenn P. A. ^{[2
]}

Lim, Patrick John Y. ^{[1
]}

机构：

[1] Univ San Carlos, Dept Chem, Cebu 6000, Philippines

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2013年 / 69卷

基金：

美国国家科学基金会;

关键词：

crystal structure; scorpionates; multidentate ligands; Cu extraction; Cu complexes; BORON-PYRAZOLE CHEMISTRY; ION SIZE DISCRIMINATION; SPECTROSCOPIC CHARACTERIZATION; POLY(PYRAZOLYL)BORATE LIGANDS; CRYSTAL-STRUCTURES; CHELATE COMPLEXES; DONOR LIGANDS; DERIVATIVES; PROTEINS; TRIS(PYRAZOLYL)METHANE;

D O I：

10.1107/S0108270113020192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [Cu(C5H10NS2)(C15H22BN6)] or (Tp(Me2))-Cu(S2CNEt2), incorporating the classic Tp(Me2) scorpionate, is relevant to blue copper protein models and to Cu extraction from waste treatment and mine-tailing leachate. The IR and UV-Vis spectra are consistent with the crystal structure.

引用

页码：977 / 980

页数：4

共 36 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2]

[Anonymous], 2007, APEX2

[3]

Bartolomäs T, 2002, Z ANORG ALLG CHEM, V628, P863, DOI 10.1002/1521-3749(200205)628:4<863::AID-ZAAC863>3.0.CO

[4]

2-I

[5] Carbonyl[hydrotris(3,5-dimethylpyrazol-1-yl)-borato]copper(I) acetonitrile solvate [J].

Blake, AJ ;

Carling, DA ;

George, MW ;

Hubberstey, P ;

Garcia, RL ;

Wilson, C .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 :m41-m42

[6]

Canada L. M. C., 2011, P 31 ANN PHIL AM AC, V31, P70

[7] Steric control of the reactivity of moderately hindered tris(pyrazolyl)borates with copper(II) salts [J].

Chia, LML ;

Radojevic, S ;

Scowen, IJ ;

McPartlin, M ;

Halcrow, MA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02) :133-140

[8] Dinuclear copper(II) trispyrazolylborate derivatives with bridging pyrazolate anions [J].

Di Nicola, Corrado ;

Marchetti, Fabio ;

Monari, Magda ;

Pandolfo, Luciano ;

Pettinari, Claudio .

INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (06) :665-668

[9] Mononuclear copper(II) hydroxo complex: Structural effect of a 3-position of tris(pyrazolyl)borates [J].

Fujisawa, K ;

Kobayashi, T ;

Fujita, K ;

Kitajima, N ;

Moro-oka, Y ;

Miyashita, Y ;

Yamada, Y ;

Okamoto, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (08) :1797-1804

[10] Structural effects on nitratocopper(II) complexes of tris (pyrazolyl)borates [J].

Fujisawa, K ;

Miyashita, Y ;

Yamada, Y ;

Okamoto, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (06) :1065-1066

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