Iron-Catalyzed Aerobic Oxidative Cross-Dehydrogenative C(sp3)H/X-H (X = C, N, S) Coupling Reactions

被引：5
作者：
Xu, Da-Zhen [1 ]
Lai, Yi-Huan [1 ]
Xu, Da-Zhen [1 ]
机构：
[1] Nankai Univ, Dept Chem, Natl Engn Res Ctr Pesticide Tianjin, Tianjin 300071, Peoples R China
来源：
SYNLETT | 2020年 / 31卷 / 18期
关键词：
iron; cross-coupling reaction; aerobic oxidative reaction; green synthesis; synthetic methods; OLEFINATION REACTION; C-SP3-H BONDS; FUNCTIONALIZATION; ACTIVATION; AMINATION; CHEMISTRY; MECHANISM;
D O I：
10.1055/s-0040-1707195
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The direct functionalization of C(sp3)-H bonds is an attractive research topic in organic synthetic chemistry. The cross-dehydrogenative coupling (CDC) reaction provides a simple and powerful tool for the construction of C-C and C-heteroatom bonds. Recently, some progress has been made in the iron-catalyzed aerobic oxidative CDC reactions. Here, we present recent developments in the direct functionalization of C(sp3)-H bonds catalyzed by simple iron salts with molecular oxygen as the terminal oxidant. 1 Introduction 2 C(sp3)-C Bond Formation 3 C(sp3)-N Bond Formation 4 C(sp3)-S(Se) Bond Formation 5 Conclusion and Outlook
引用
收藏
页码：1753 / 1759
页数：7
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