Enhanced Interfacial Interaction and Electronic Properties of Novel Conducting Kenaf/Polyaniline Biofibers

被引:19
作者
Abd Razak, Saiful Izwan [1 ]
Rahman, Wan Aizan Wan Abdul [1 ]
Hashim, Shahrir [1 ]
Yahya, Mohd Yazid [2 ]
机构
[1] Univ Teknol Malaysia, Fac Chem Engn, Dept Polymer Engn, Skudai 81310, Johor, Malaysia
[2] Univ Teknol Malaysia, Ctr Composites, Skudai 81310, Johor, Malaysia
关键词
Electrical conductivity; Kenaf fiber; Mechanical properties; Polyaniline; CARBON NANOTUBE/POLYANILINE NANOCOMPOSITES; FIBER COMPOSITES; EPOXY-RESIN; POLYANILINE; ACID; BIOCOMPOSITES; POLYMERS; DENSITY;
D O I
10.1080/03602559.2012.718401
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conducting kenaf/polyaniline (KF/PANI) biofibers were successfully prepared via in situ oxidative polymerization. It was demonstrated, for the first time, the possibility of imparting new electronic properties on KF by coating with acid-doped PANI. The morphological analysis revealed three different PANI morphologies on the KF, depending on the type of acid doping. Enhanced interaction was achieved between the fiber-PANI surfaces, mainly from the p - p interactions. The newly developed conducting biofibers achieved enhancement in DC conductivity up to fivefold compared to the unmodified KF. Mechanical test on the conducting biofibers revealed no significant loss in the tensile properties.
引用
收藏
页码:51 / 57
页数:7
相关论文
共 29 条
[1]   Surface topography of kenaf (Hibiscus cannabinus) sized papers [J].
Ashori, Alireza ;
Raverty, Warwick D. ;
Vanderhoek, Nafty ;
Ward, John V. .
BIORESOURCE TECHNOLOGY, 2008, 99 (02) :404-410
[2]   Control of polyaniline conductivity and contact angles by partial protonation [J].
Blinova, Natalia V. ;
Stejskal, Jaroslav ;
Trchova, Miroslava ;
Prokes, Jan .
POLYMER INTERNATIONAL, 2008, 57 (01) :66-69
[3]  
Chand N, 2010, BIORESOURCES, V5, P1789
[4]   Synthesis and characterization of polyaniline prepared in formic acid medium [J].
Dan, A ;
Sengupta, PK .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (02) :991-999
[5]   The Use of Infrared Thermography in Detecting the Defects in Kenaf-Poly Urethane Composites [J].
Dashtizadeh, Zahra ;
Ali, Aidy ;
Abdan, Khalina ;
Behmanesh, Mohammad .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2012, 51 (11) :1155-1162
[6]   Fabrication of Schottky diode based on Zn electrode and polyaniline doped with 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt [J].
Ebrahim, Shaker Mabrouk .
JOURNAL OF POLYMER RESEARCH, 2009, 16 (05) :481-487
[7]  
EDWARDS HGM, 1997, SPECTROCHIM ACTA A, V53, P2382
[8]   Development of Green Insulation Boards from Kenaf Fibres and Polyurethane [J].
Ibraheem, S. A. ;
Ali, Aidy ;
Khalina, A. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2011, 50 (06) :613-621
[9]   INFLUENCE OF THE DOPING CONDITIONS ON THE SURFACE ENERGIES OF CONDUCTING POLYMERS [J].
LIU, MJ ;
TZOU, K ;
GREGORY, RV .
SYNTHETIC METALS, 1994, 63 (01) :67-71
[10]   Studies on mechanical performance of biofibre/glass reinforced polyester hybrid composites [J].
Mishra, S ;
Mohanty, AK ;
Drzal, LT ;
Misra, M ;
Parija, S ;
Nayak, SK ;
Tripathy, SS .
COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (10) :1377-1385