Synthesis and structural characterization of macrocyclic carbohydrate derivatives obtained from catalytic metathesis reaction with chloro-aryloxide complexes of tungsten

被引：25

作者：

Descotes, G

Ramza, J

Basset, JM

Pagano, S

Gentil, E

Banoub, J

机构：

[1] LAB CHIM ORGANOMET SURFACE,CNRS UMR 9986,F-69626 VILLEURBANNE,FRANCE

[2] FISHERIES & OCEANS CANADA,EXPTL SCI DIV,ST JOHNS,NF A1C 5X1,CANADA

[3] MEM UNIV NEWFOUNDLAND,DEPT BIOCHEM,ST JOHNS,NF A1B 3X9,CANADA

来源：

TETRAHEDRON | 1996年 / 52卷 / 33期

关键词：

D O I：

10.1016/0040-4020(96)00612-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tungsten aryloxo-complex 1 catalyses the intramolecular metathesis reactions of di- and tri-substituted omega-unsaturated glucose, and glucosamine derivatives, yielding bicyclic carbohydrate-based compounds 12, 13, 14, 15, containing 12-, and 14-atoms rings. Electrospray tandem mass spectrometry was used for the structural characterization of these novel bicyclic carbohydrate compounds. Copyright (C) 1996 Elsevier Science Ltd

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页码：10903 / 10920

页数：18

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