Orientation of bromination in bay-region of perylene diimides

被引：27
作者：
Zhang, Xin [1 ]
Zhan, Chuanlang [1 ]
Zhang, Xinliang [1 ]
Yao, Jiannian [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, CAS Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
来源：
TETRAHEDRON | 2013年 / 69卷 / 38期
关键词：
Orientation; Bromination; Perylene diimides; VERSATILE BUILDING-BLOCKS; HIGH-MOBILITY; CHARGE-TRANSPORT; BISIMIDE DYES; SEMICONDUCTORS; DERIVATIVES; TRANSISTORS; ASSEMBLIES; CRYSTALS; DIMERS;
D O I：
10.1016/j.tet.2013.07.035
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We found that the entering position of the bromination in the bay-region (e.g., 1,6,7,12-positions) was precisely determined by the orientation director(s), either individually or cooperatively. In particular, a combination of two directors shows precisely positioning for the third entering bromo with an effect of '1+1>2'. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8155 / 8160
页数：6
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