Synthesis, structure, and CO2 reactivity of a two-coordinate (carbene)copper(I) methyl complex

被引：165

作者：

Mankad, NP ^{[1
]}

Gray, TG ^{[1
]}

Laitar, DS ^{[1
]}

Sadighi, JP ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 06期

关键词：

D O I：

10.1021/om034368r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two-coordinate copper(I) acetate and copper(I) methyl complexes, bearing an N-heterocyclic carbene (NHC) supporting ligand, have been synthesized and structurally characterized, and the stability of the monodentate acetate has been examined by DFT calculations. The methyl complex readily inserts carbon dioxide at ambient temperature and pressure, regenerating the acetate in near-quantitative yield.

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页码：1191 / 1193

页数：3

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