Sustainable Recycling of Benzoic Acid Production Waste: Green and Highly Efficient Methods To Separate and Recover High Value-Added Conjugated Aromatic Compounds from Industrial Residues

被引：6

作者：

Zhang, Xin ^{[1
,2
]}

Qiao, Pengwei ^{[1
]}

Ji, Xuan ^{[1
]}

Han, Junbin ^{[1
]}

Liu, Lili ^{[1
]}

Weeks, Brandon L. ^{[2
]}

Yao, Qingwei ^{[3
]}

Zhang, Zhao ^{[1
]}

机构：

[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China

[2] Texas Tech Univ, Dept Chem Engn, Lubbock, TX 79409 USA

[3] Sphinx Sci Lab Corp, Sycamore, IL 60178 USA

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 08期

关键词：

Sustainable chemistry; Benzoic acid industrial residue; 9-Fluorenone; 6H-Benzo[c]chromen-6-one; Biphenyl carboxylic acids; OXIDATION; ISOMERS; TEMPERATURE; CATALYSTS; TOLUENE; RESINS; WATER; AIR;

D O I：

10.1021/sc400059J

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Industrial residues formed in the industrial production of benzoic acid by cobalt-catalyzed oxidation of toluene are traditionally disposed as waste materials and often burnt or buried. It therefore may become a significant source of environmental pollution. In this report, we describe simple techniques to obtain high value conjugated aromatic compounds, including 9-fluorenone, 6H-benzo[c]chromen-6-one, biphenyl-3-carboxylic acid, and biphenyl-4-carboxylic acid, from benzoic acid industrial residue using inexpensive alkalis and acids. The separation methods involve simple and mild procedures with high economic effectiveness and low environmental contamination.

引用

页码：974 / 981

页数：8

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