Synthesis of Aldehydic Ribonucleotide and Amino Acid Precursors by Photoredox Chemistry

被引：84

作者：

Ritson, Dougal J. ^{[1
]}

Sutherland, John D. ^{[1
]}

机构：

[1] MRC Lab Mol Biol, Cambridge CB2 0QH, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 22期

基金：

英国医学研究理事会; 英国工程与自然科学研究理事会;

关键词：

amino acids; nucleotides; photochemical reactions; reduction; solvated electrons; FERROCYANIDE;

D O I：

10.1002/anie.201300321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Light work: UV irradiation of a system formed by adding copper(I) cyanide to an aqueous solution of glycolonitrile, sodium phosphate, and hydrogen sulfide efficiently generates aldehyde precursors to the building blocks of RNA and proteins. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：5845 / 5847

页数：3

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