Selected macroscopic properties of liquid crystalline elastomers

被引:89
作者
Brand, HR
Pleiner, H [1 ]
Martinoty, P
机构
[1] Max Planck Inst Polymer Res, D-55021 Mainz, Germany
[2] Univ Bayreuth, Dept Phys, D-95440 Bayreuth, Germany
[3] ULP, CNRS, UMR 7507, Inst Mecan Fluides & Solides, F-67000 Strasbourg, France
关键词
D O I
10.1039/b512693m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this short review we give an overview of selected macroscopic properties of sidechain liquid crystalline elastomers (LCEs) focusing on three closely related topics (a) the influence of relative rotations between the director and the strain field on various reorientation instabilities, (b) the nonlinear stress-strain curves for the polydomain-monodomain transition and for the reorientation transition in LCE monodomains and (c) the shear mechanical response of LCEs in the linear regime. We consider only already existing real materials and do not discuss hypothetical "ideal" systems. We conclude that all observations reported to date can be accounted for without invoking the concept of soft elasticity, but instead relying on macroscopic dynamics in the linear and the nonlinear domain.
引用
收藏
页码:182 / 189
页数:8
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