Palladium-Catalyzed Direct Arylation of C-H Bond To Construct Quaternary Carbon Centers: The Synthesis of Diarylfluorene

被引：34

作者：

Cao, Xiao ^{[1
,2
]}

Yang, Weidong ^{[1
,2
]}

Liu, Chao ^{[3
]}

Wei, Fuliang ^{[1
,2
]}

Wu, Kun ^{[3
]}

Sun, Wei ^{[1
,2
]}

Song, Juan ^{[1
,2
]}

Xie, Linghai ^{[1
,2
]}

Huang, Wei ^{[1
,2
]}

机构：

[1] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Display, Nanjing 210046, Jiangsu, Peoples R China

[2] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China

[3] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 12期

基金：

中国国家自然科学基金;

关键词：

LIGHT-EMITTING-DIODES; CROSS-COUPLING REACTIONS; CONJUGATE ADDITION; OPTICAL-PROPERTIES; ARYLBORONIC ACIDS; STEREOCENTERS; POLYFLUORENE; DERIVATIVES; ALKYLATION; POLYMERS;

D O I：

10.1021/ol4013052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel Pd-catalyzed C-H functionalization reaction was developed to construct a quaternary carbon center with high yield. This reaction provides an efficient method for the synthesis of 9,9'-diarylfluorenes by direct arylation of monoarylfluorene.

引用

页码：3102 / 3105

页数：4

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