Can Polymorphism be Used to form Branched Metal Nanostructures?

被引:77
作者
LaGrow, Alec P. [1 ,2 ]
Cheong, Soshan [1 ,2 ,3 ]
Watt, John [1 ,2 ]
Ingham, Bridget [3 ]
Toney, Michael F. [4 ]
Jefferson, David A. [5 ]
Tilley, Richard D. [1 ,2 ]
机构
[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington 6012, New Zealand
[2] Victoria Univ Wellington, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington 6012, New Zealand
[3] Ind Res Ltd, Lower Hutt 5040, New Zealand
[4] SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA
[5] Univ Cambridge, Chem Labs, Cambridge CB2 1EW, England
关键词
nickel; metal; nanoparticle; nanostructures; branched; MONODISPERSE NICKEL NANOPARTICLES; MAGNETIC-PROPERTIES; AMMONIA BORANE; NANOCRYSTALS; NANOWIRES; GROWTH; NI; SUPERLATTICES; ULTRATHIN; PLATINUM;
D O I
10.1002/adma.201204366
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Branched metal nanostructures are of great technological importance because of their unique size-and shape-dependent properties. A kinetically controlled synthesis that uses polymorphism to produce branched nickel nanoparticles is presented. These nanoparticles consist of a face-centred cubic (fcc) core and extended arms of alternating fcc and hexagonal close-packed (hcp) nickel phases.
引用
收藏
页码:1552 / 1556
页数:5
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