Pd-catalyzed borylative cyclisation of 1,7-enynes

被引:44
|
作者
Pardo-Rodriguez, Virtudes [1 ]
Bunuel, Elena [1 ]
Collado-Sanz, Daniel [1 ]
Cardenas, Diego J. [1 ]
机构
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain
关键词
ENYNE METATHESIS; SKELETAL REORGANIZATION; CYCLOISOMERIZATION; 1,6-ENYNES; GOLD; PLATINUM; N-ENYNES; SCOPE; TOOL;
D O I
10.1039/c2cc34468h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of a variety of 1,7-enynes with bis(pinacolato) diboron catalysed by Pd bis(trifluoroacetate) affords homoallylic and allylic boronates containing a six membered carbo- or hetero-cycle, by formation of C-C and C-B bonds
引用
收藏
页码:10517 / 10519
页数:3
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