Cu2ZnSnS4 thin films: Facile and cost-effective preparation by RF-magnetron sputtering and texture control

被引：63

作者：

Wang, Jiansheng ^{[1
]}

Li, Song ^{[1
]}

Cai, Jiajia ^{[1
]}

Shen, Bo ^{[1
]}

Ren, Yuping ^{[1
]}

Qin, Gaowu ^{[1
]}

机构：

[1] Northeastern Univ, Key Lab Anisotropy & Texture Mat MoE, Shenyang 110819, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2013年 / 552卷

关键词：

Cu2ZnSnS4 (CZTS); RF magnetron sputtering; Photovoltaic semiconductor; Texture control; LIGHT-ABSORPTION; GROWTH;

D O I：

10.1016/j.jallcom.2012.11.082

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cu2ZnSnS4 photovoltaic semiconductor films (CZTS) were deposited by RF magnetron sputtering using a home-made Cu2S-ZnS-SnS2-S mixed powder target. The phase information of the CZTS films was studied via X-ray diffraction and Raman scattering techniques. The films prepared at substrate temperatures between 150 degrees C and 200 degrees C exhibited strong preferential orientation of grains along < 112 >. Higher substrate temperature (over 200 degrees C) induced a flower-like structure of CZTS films without preferred orientation and the light absorption coefficients were largely enhanced. The energy band gaps of CZTS films deposited at different substrate temperatures were approximate 1.7 eV. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：418 / 422

页数：5

共 26 条

[1] Cao LY, 2009, NAT MATER, V8, P643, DOI [10.1038/nmat2477, 10.1038/NMAT2477]
[2] The Next Frontier: Electrodeposition for Solar Cell Fabrication
Deligianni, Hariklia
Ahmed, Shafaat
Romankiw, Lubomyr T.
[J]. ELECTROCHEMICAL SOCIETY INTERFACE, 2011, 20 (02) : 47 - 53
[3] Strong Geometrical Dependence of the Absorption of Light in Arrays of Semiconductor Nanowires
Diedenhofen, Silke L.
Janssen, Olaf T. A.
Grzela, Grzegorz
Bakkers, Erik P. A. M.
Rivas, Jaime Gomez
[J]. ACS NANO, 2011, 5 (03) : 2316 - 2323
[4] Cu2ZnSnS4 thin film solar cells from electroplated precursors: Novel low-cost perspective
Ennaoui, A.
Lux-Steiner, M.
Weber, A.
Abou-Ras, D.
Koetschau, I.
Schock, H. -W.
Schurr, R.
Hoelzing, A.
Jost, S.
Hock, R.
Voss, T.
Schulze, J.
Kirbs, A.
[J]. THIN SOLID FILMS, 2009, 517 (07) : 2511 - 2514
[5] Study of polycrystalline Cu2ZnSnS4 films by Raman scattering
Fernandes, P. A.
Salome, P. M. P.
da Cunha, A. F.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (28) : 7600 - 7606
[6] A study of ternary Cu2SnS3 and Cu3SnS4 thin films prepared by sulfurizing stacked metal precursors
Fernandes, P. A.
Salome, P. M. P.
da Cunha, A. F.
[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (21)
[7] Growth and Raman scattering characterization of Cu2ZnSnS4 thin films
Fernandes, P. A.
Salome, P. M. P.
da Cunha, A. F.
[J]. THIN SOLID FILMS, 2009, 517 (07) : 2519 - 2523
[8] Texture and electronic activity of grain boundaries in Cu(In,Ga)Se2 thin films
Hanna, G
Glatzel, T
Sadewasser, S
Ott, N
Strunk, HP
Rau, U
Werner, JH
[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2006, 82 (01): : 1 - 7
[9] Hanna G., 2004, THESIS U STUTTGART
[10] Light absorption by colloidal semiconductor quantum dots
Hens, Zeger
Moreels, Iwan
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (21) : 10406 - 10415

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