Rhodium(III)-Catalyzed Annulation of Azomethine Ylides with Alkynes via CH Activation

被引：81

作者：

Chen, Yuye ^{[1
,2
]}

Wang, Fen ^{[1
]}

Zhen, Wencui ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

[2] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210014, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 2-3期

关键词：

alkynes; CH activation; cyclization; indenamines; rhodium; H BOND ACTIVATION; OXIDATIVE OLEFINATION; AROMATIC KETIMINES; INTERNAL ALKYNES; FUNCTIONALIZATION; RH; BENZAMIDES; RUTHENIUM; ARYLATION; COUPLING/CYCLIZATION;

D O I：

10.1002/adsc.201200924

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The rhodium(III)-catalyzed coupling of azomethine ylides with alkynes via CH activation has been developed for the synthesis of indenamines in moderate to high yields. The coupled products can be further oxidized to indenones and derivatives.

引用

页码：353 / 359

页数：7

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