Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under exceedingly mild conditions -: a novel possibility of carbon dioxide activation

被引：118

作者：

Joó, F

Laurenczy, G

Nádasdi, L

Elek, J

机构：

[1] L Kossuth Univ, Hungarian Acad Sci, Inst Phys Chem, H-4010 Debrecen, Hungary

[2] L Kossuth Univ, Hungarian Acad Sci, Rs Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary

[3] Univ Lausanne, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a902368b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water soluble ruthenium(II)- and rhodium(I)-phosphine complexes catalyze the hydrogenation of aqueous HCO3 - to HCO2- under mild conditions with turnover frequencies up to 262 TO h(-1).

引用

页码：971 / 972

页数：2

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