A benign initiating system for cationic polymerization of isobutyl vinyl ether: Silver salt/aryl(alkyl) halide/lewis base

被引：5

作者：

Lin, Li ^{[1
]}

Zhang, Guangyou ^{[2
]}

Kodama, Koichi ^{[1
]}

Yasutake, Mikio ^{[1
]}

Hirose, Takuji ^{[1
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, Sakura Ku, Saitama 3388570, Japan

[2] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2015年 / 53卷 / 17期

关键词：

cationic polymerization; poly(vinyl ethers); aryl(alkyl) halide; additives; alkyl sulfide; LIVING POLYMERIZATION; HYDROGEN IODIDE; MONOMERS; CHLORIDE; SALTS; DISCOVERY; CATALYSTS; POLYMERS; ETALCL2; DESIGN;

D O I：

10.1002/pola.27656

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aryl(alkyl) halides and silver salts were studied as environmentally benign initiating systems for cationic polymerization of isobutyl vinyl ether (IBVE). The reactivity of the benzyl cations could be effectively controlled by using dimethyl sulfide (Me2S) as an additive, which was shown to be an effective Lewis base (LB), and diethyl ether as a reaction solvent. Detailed study of various benzyl cations and the order of addition of the reagents revealed that the reaction was controlled by the electronic and steric features of aryl(alkyl) halides, LBs, and IBVE, and a plausible reaction mechanism was presented. (c) 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2050-2058

引用

页码：2050 / 2058

页数：9

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