Reactions of allyl alcohols and boronic acids with trifluoromethanesulfonyl hypervalent iodonium ylide under copper-catalysis

被引：51

作者：

Arimori, Sadayuki ^{[1
]}

Takada, Masahiro ^{[1
]}

Shibata, Norio ^{[1
]}

机构：

[1] Nagoya Inst Technol, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 45期

关键词：

SILYL ENOL ETHERS; OXIDATIVE TRIFLUOROMETHYLTHIOLATION; ENANTIOSELECTIVE FLUORINATION; SILVER(I) TRIFLUOROMETHANETHIOLATE; TERMINAL ALKYNES; ARYL; REAGENT; SULFOXIDES; KETONES;

D O I：

10.1039/c5dt02214b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoromethylsulfinyl and trifluoromethylthio groups are both important substituents for pharmaceuticals, agrochemicals and functional materials. We herein report the trifluoromethylthiolation of allyl alcohols 2 with trifluoromethanesulfonyl hypervalent iodonium ylide 1 under copper catalysis to provide trifluoromethylsulfinyl compounds 3. Trifluoromethylthiolation of boronic acids 4 with 1 furnished trifluoromethylthio compounds 5.

引用

页码：19456 / 19459

页数：4

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