Chemically activated SHS in synthesis of refractory carbide powders

被引：14

作者：

Kharatyan, SL ^{[1
]}

Nersisyan, HH ^{[1
]}

机构：

[1] NAS RA, Nalbandyan Inst Chem Phys, Yerevan 375044, Armenia

来源：

PROGRESS IN SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS | 2002年 / 217卷

关键词：

carbide; chemical activation; combustion synthesis; halogen-containing additives;

D O I：

10.4028/www.scientific.net/KEM.217.83

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The mechanism of combustion in simple and complex carbide systems as Me - C (where Me - Ti, W, Mo, Cr, Nb, etc.) and SiO2-Al-C in the presence of halogen-containing organic additives is investigated. It is shown that the halogenides of metals, which form during combustion strongly intensify process of mass transfer and promote proceeding of carbidization at rather low temperatures, including the low-exothermic and hard burning systems. Phenomenon and effects earlier unknown in SHS are found out and investigated. Macrokinetic peculiarities of combustion for carbide systems under the conditions of activation and main advantages of the approach offered are revealed.

引用

页码：83 / 91

页数：9

共 50 条

[1] SHS of Ultrafine and Nanosized Refractory Powders: An Autoreview
Borovinskaya, I. P.
Barinova, T. V.
Vershinnikov, V. I.
Ignat'eva, T. I.
INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS, 2010, 19 (02) : 114 - 119
[2] SHS of ultrafine and nanosized refractory powders: An autoreview
I. P. Borovinskaya
T. V. Barinova
V. I. Vershinnikov
T. I. Ignat’eva
International Journal of Self-Propagating High-Temperature Synthesis, 2010, 19 (2) : 114 - 119
[3] Granulation Effect on Chemically Activated SHS of MgAlON
D. I. Abzalov
T. G. Akopdzhanyan
N. I. Abzalov
R. A. Kochetkov
V. V. Grachev
International Journal of Self-Propagating High-Temperature Synthesis, 2023, 32 : 338 - 343
[4] Granulation Effect on Chemically Activated SHS of MgAlON
Abzalov, D. I.
Akopdzhanyan, T. G.
Abzalov, N. I.
Kochetkov, R. A.
Grachev, V. V.
INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS, 2023, 32 (04) : 338 - 343
[5] Chemically-assisted combustion synthesis of silicon carbide from elemental powders
Puszynski, JA
Miao, SX
INNOVATIVE PROCESSING AND SYNTHESIS OF CERAMICS, GLASSES, AND COMPOSITES II, 1999, 94 : 13 - 21
[6] KINETICS OF OXIDATION SHS OF TITANIUM CARBIDE AND TITANIUM AND CHROMIUM DOUBLE CARBIDE POWDERS IN AIR
KOMRATOV, GN
POWDER METALLURGY AND METAL CERAMICS, 1993, 32 (06) : 509 - 511
[7] SYNTHESIS OF REFRACTORY-METAL CARBIDE POWDERS VIA MICROWAVE CARBOTHERMAL REDUCTION
HASSINE, NA
BINNER, JGP
CROSS, TE
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 1995, 13 (06): : 353 - 358
[8] Thermal plasma & SHS synthesis of intermetallic powders
Beaudoin, D
Puszynski, J
Gitzhofer, F
Jurewicz, J
PROCEEDINGS OF THE NINTH INTERNATIONAL CONFERENCE ON HIGH TEMPERATURE MATERIALS CHEMISTRY, 1997, 97 (39): : 587 - 594
[9] Tantalum carbide products from chemically-activated combustion synthesis reactions
Musa, Clara
Licheri, Roberta
Montinaro, Selena
Orru, Roberto
Cao, Giacomo
CERAMICS INTERNATIONAL, 2017, 43 (15) : 12844 - 12850
[10] Activated sintering of TiC-TiB2SHS-powders
Vallauri, D
Martins, IM
Deorsola, F
Amato, I
Delmas, F
Oliveira, MM
ADVANCED MATERIALS FORUM II, 2004, 455-456 : 560 - 563

← 1 2 3 4 5 →