A ZnO nanorod/nanoparticle hierarchical structure synthesized through a facile in situ method for dye-sensitized solar cells

被引:24
作者
Gao, Rui [1 ]
Cui, Yixiu [1 ]
Liu, Xiaojiang [1 ]
Wang, Liduo [2 ]
Cao, Guozhong [3 ,4 ]
机构
[1] China Acad Engn Phys, Inst Elect Engn, Mianyang 621900, Sichuan, Peoples R China
[2] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelectron & Mol Engn, Beijing 100084, Peoples R China
[3] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[4] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100085, Peoples R China
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
NANOWIRE ARRAYS; INTERFACE PRECIPITATION; HIGH EFFICIENCIES; ROOM-TEMPERATURE; ZINC FOIL; PHOTOELECTRODES; NANOSTRUCTURES; NANOPARTICLES; SUBSTRATE; NANOCRYSTALLITES;
D O I
10.1039/c3ta15276f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel ZnO nanorod/nanoparticle (NR/NP) hierarchical structure on a zinc foil has been fabricated through a chemical bath deposition method. When used as a flexible photoanode for DSSCs, such a structure demonstrated enhanced dye-loading and electron lifetime as compared to the NR structure. It also retarded the charge recombination while maintaining the electron diffusion length of the NR structure. As a result, the power conversion efficiency of the DSSCs based on the NR/NP structure increased from 1.35% to 3.63% with a 169% enhancement as compared to that based on ZnO NRs.
引用
收藏
页码:4765 / 4770
页数:6
相关论文
共 36 条
[1]   Dye-sensitized solar cells based on semiconductor morphologies with ZnO nanowires [J].
Baxter, JB ;
Aydil, ES .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (05) :607-622
[2]   Hierarchically assembled ZnO nanoparticles on high diffusion coefficient ZnO nanowire arrays for high efficiency dye-sensitized solar cells [J].
Chen, Liang-Yih ;
Yin, Yu-Tung .
NANOSCALE, 2013, 5 (05) :1777-1780
[3]   Branched ZnO nanostructures as building blocks of photoelectrodes for efficient solar energy conversion [J].
Chen, Wei ;
Qiu, Yongcai ;
Yang, Shihe .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (31) :10872-10881
[4]   A new ZnO nanotetrapods/SnO2 nanoparticles composite photoanode for high efficiency flexible dye-sensitized solar cells [J].
Chen, Wei ;
Qiu, Yongcai ;
Yang, Shihe .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (32) :9494-9501
[5]   ZnO hierarchical structures for efficient quasi-solid dye-sensitized solar cells [J].
Cheng, Chun ;
Shi, Yantao ;
Zhu, Chao ;
Li, Wei ;
Wang, Lin ;
Fung, Kwok Kwong ;
Wang, Ning .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (22) :10631-10634
[6]   Constructing nanorod-nanoparticles hierarchical structure at low temperature as photoanodes for dye-sensitized solar cells: combining relatively fast electron transport and high dye-loading together [J].
Dong, Haopeng ;
Wang, Liduo ;
Gao, Rui ;
Ma, Beibei ;
Qiu, Yong .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (48) :19389-19394
[7]   ZnO Nanocrystallite Aggregates Synthesized through Interface Precipitation for High Efficiency Dye-sensitized Solar Cells [J].
Gao, Rui ;
Liang, Zhiqiang ;
Tian, Jianjun ;
Zhang, Qifeng ;
Wang, Liduo ;
Cao, Guozhong .
FULLERENES, NANOTUBES, AND CARBON NANOSTRUCTURES - 221ST ECS MEETING, 2013, 45 (20) :127-135
[8]   A ZnO nanorod layer with a superior light-scattering effect for dye-sensitized solar cells [J].
Gao, Rui ;
Liang, Zhiqiang ;
Tian, Jianjun ;
Zhang, Qifeng ;
Wang, Liduo ;
Cao, Guozhong .
RSC ADVANCES, 2013, 3 (40) :18537-18543
[9]   ZnO nanocrystallite aggregates synthesized through interface precipitation for dye-sensitized solar cells [J].
Gao, Rui ;
Liang, Zhiqiang ;
Tian, Jianjun ;
Zhang, Qifeng ;
Wang, Liduo ;
Cao, Guozhong .
NANO ENERGY, 2013, 2 (01) :40-48
[10]  
Gao R, 2013, NANOSCALE, V5, P1894, DOI [10.1039/c2nr33599a, 10.1039/C2NR33599A]