Diaquabis(N,N-diethylnicotinamide-N-1)bis(2-hydroxybenzoato-O)cobalt(II)

被引:41
作者
Hokelek, T [1 ]
Necefoglu, H [1 ]
机构
[1] KAFKAS UNIV,DEPT CHEM,KARS,TURKEY
关键词
D O I
10.1107/S0108270196013170
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title monomeric centrosymmetric cobalt complex, [Co(C7H5O3)(2)(C10H14N2O)(2)(H2O)(2)], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All Ligands are coordinated to the Co atom as monodentate Ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) Angstrom. The water molecules are hydrogen bonded to the carboxyl O atoms [O ... O 2.687 (5) Angstrom].
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页码:187 / 189
页数:3
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