Alternating ring-opening metathesis copolymerization of bicyclo[2.2.1]hept-2-ene and cyclopentene

被引：26

作者：

AlSamak, B ^{[1
]}

Carvill, AG ^{[1
]}

Hamilton, JG ^{[1
]}

Rooney, JJ ^{[1
]}

Thompson, JM ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 21期

关键词：

D O I：

10.1039/a705046a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Almost alternating copolymers of bicyclo[2.2.1]hept-2-ene and cyclopentene have been formed by ring-opening metathesis polymerization using a RuCl3-phenol catalyst system; this highly novel result is attributed to differential steric influences exerted by a hydrogen-bonded solvent cage which encloses the catalyst site.

引用

页码：2057 / 2058

页数：2

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