Selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over intercalated vanadium phosphate oxides

被引:65
作者
Grasset, Fabien L. [1 ,2 ]
Katryniok, Benjamin [2 ,3 ]
Paul, Sebastien [2 ,3 ]
Nardello-Rataj, Veronique [1 ,4 ,5 ]
Pera-Titus, Marc [6 ]
Clacens, Jean-Marc [6 ]
De Campo, Floryan [6 ]
Dumeignil, Franck [1 ,2 ,5 ,7 ]
机构
[1] Univ Lille Nord France, F-59000 Lille, France
[2] Univ Lille 1, Ctr Hyperfrequences & Semicond, CNRS, Unite Catalyse & Chim Solide,UMR 8181, F-59655 Villeneuve Dascq, France
[3] Ecole Cent Lille, UCCS, CNRS, UMR 8181, F-59651 Villeneuve Dascq, France
[4] Equipe Accueil Chim Mol & Formulat EA CMF 4478, F-59652 Villeneuve Dascq, France
[5] Univ Lille 1, F-59650 Villeneuve Dascq, France
[6] UMI 3464 CNRS Rhodia China, Ecoefficient Prod & Proc Lab E2P2L, Shanghai 201108, Peoples R China
[7] Inst Univ France, F-75005 Paris, France
关键词
AEROBIC OXIDATION; CATALYSTS; BIOMASS; DERIVATIVES; ACID;
D O I
10.1039/c3ra41890a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The selective oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) was studied over vanadium phosphate oxide (VPO)-based heterogeneous catalysts in the liquid phase. The selectivity to DFF was highly increased when using intercalated vanadium phosphate oxides under mild conditions (1 atm of oxygen, 110 degrees C) in an aromatic solvent. We found that the length of the intercalated ammonium alkyl chain had no clear influence on the catalytic performances, and a maximum yield of 83% could be achieved over C14VOPO4 and C14VOHPO4 after 6 h of reaction. Recycling of the catalyst was successfully performed, and we further obtained some insights in the reaction pathway: while the desired oxidation reaction indeed proceeded over the catalyst, the formation of by-products was linked to the presence of free radicals in solution.
引用
收藏
页码:9942 / 9948
页数:7
相关论文
共 50 条
[41]   Catalytic Conversion of Fructose and 5-Hydroxymethylfurfural into 2,5-Diformylfuran over SBA-15 Supported Ruthenium Catalysts [J].
Wang, Fan ;
Jiang, Liang ;
Wang, Junmei ;
Zhang, Zehui .
ENERGY & FUELS, 2016, 30 (07) :5885-5892
[42]   Palygorskite-supported ruthenium catalysts for the efficient selective oxidation of 5-hydroxymethylfurfural to 2, 5-diformylfuran [J].
Zhong, Xuemin ;
Yuan, Peng ;
Sadjadi, Samahe ;
Liu, Dong ;
Wei, Yanfu .
APPLIED CLAY SCIENCE, 2023, 242
[43]   Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide [J].
Liu, Bing ;
Zhang, Zehui ;
Lv, Kangle ;
Deng, Kejian ;
Duan, Hongmin .
APPLIED CATALYSIS A-GENERAL, 2014, 472 :64-71
[44]   The functional and synergetic optimization of the thermal-catalytic system for the selective oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran: a review [J].
Zhang, Weijie ;
Qian, Hengli ;
Hou, Qidong ;
Ju, Meiting .
GREEN CHEMISTRY, 2023, 25 (03) :893-914
[45]   Efficient and Selective Aerobic Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran at Moderate Reaction Conditions with Design of Experiments Approach [J].
Derflinger, Christoph ;
Kamm, Birgit ;
Paulik, Christian ;
Meissner, Gisa ;
Spod, Hendrik .
CHEMISTRYSELECT, 2022, 7 (36)
[46]   A Carbon Catalyst Co-Doped with P and N for Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2,5-Diformylfuran [J].
Zhang, Huifa ;
Clark, James H. ;
Geng, Tong ;
Zhang, Huixian ;
Cao, Fahai .
CHEMSUSCHEM, 2021, 14 (01) :456-466
[47]   Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts [J].
Rodikova, Yulia ;
Zhizhina, Elena .
REACTION KINETICS MECHANISMS AND CATALYSIS, 2020, 130 (01) :403-415
[48]   Selective Oxidation of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran over the Oxygen-Vacancy-Rich Ru/MnO2 Catalyst [J].
Qin, Chuan ;
Guo, Xusheng ;
Si, Yuxi ;
Huang, Yuanchao ;
Cheng, Youwei .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2025,
[49]   Photocatalytic Partial Oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-Diformylfuran (DFF) Over a Covalent Triazine Framework in Water [J].
Ayed, Cyrine ;
Huang, Wei ;
Kizilsavas, Goenuel ;
Landfester, Katharina ;
Zhang, Kai A. I. .
CHEMPHOTOCHEM, 2020, 4 (08) :571-576
[50]   Cu catalyzed oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran and 2,5-furandicarboxylic acid under benign reaction conditions [J].
Hansen, Thomas S. ;
Sadaba, Irantzu ;
Garcia-Suarez, Eduardo J. ;
Riisager, Anders .
APPLIED CATALYSIS A-GENERAL, 2013, 456 :44-50