Influence of temperature on curative interactions with the participation of metal carboxylates as adhesive promoters:: the interactions of Cu(II) hexadecanoate with stearic acid, N,N′-dicyclohexylbenzothiazole-2-sulfenamide, sulfur and zinc oxide

被引：11

作者：

Jóna, E

Pajtásová, M

Ondrusová, D

Simon, P

机构：

[1] Univ Trencin, Fac Ind Technol, Dept Chem & Technol Inorgan Mat, Puchov 02032, Slovakia

[2] Slovak Univ Technol Bratislava, Dept Phys Chem, Bratislava 81237, Slovakia

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2002年 / 63卷 / 01期

关键词：

DSC calorimetry; IR; EPR spectroscopy; X-ray analysis; curative interactions; metal carboxylates;

D O I：

10.1016/S0165-2370(01)00138-3

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The influence of temperature on the interactions between Cu(II) hexadecanoate (CuC16) and N,N'-dicyclohexylbenzothiazole-2-sulfenamide (DCBS), stearic acid, sulfur and zinc oxide (ZnO) were studied by differential scanning calorimetry, infrared spectroscopy, electron paramagnetic resonance spectroscopy and X-ray analysis in the absence of rubber. Comparison of the results reveals that in most cases physical processes (dissolution, melting) occurred in the studied systems. However, the most favorable thermal reaction appears to be the formation of Cu(II) complexes with DCBS (or DCBS fragments) and the formation of zinc stearate in the presence of stearic acid and ZnO on the action of heat. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：17 / 27

页数：11

共 27 条

[1] PROPERTIES OF MOLTEN CARBOXYLATES .4. QUANTITATIVE DIFFERENTIAL THERMAL-ANALYSIS STUDY OF MELTING AND MESOPHASE FORMATION IN SOME LEAD(II) CARBOXYLATES [J].