Selective deprotection of silyl ethers

被引：83

作者：

Crouch, R. David ^{[1
]}

机构：

[1] Dickinson Coll, Dept Chem, Carlisle, PA 17013 USA

来源：

TETRAHEDRON | 2013年 / 69卷 / 11期

关键词：

Deprotection; Desilylation; Silyl ethers; Silyl protecting groups; ENANTIOSELECTIVE TOTAL-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; STEREOSELECTIVE TOTAL-SYNTHESIS; TERT-BUTYLDIMETHYLSILYL ETHERS; PROTECTING-GROUP-FREE; ASYMMETRIC TOTAL-SYNTHESIS; RING-CLOSING METATHESIS; DIELS-ALDER REACTION; STEREOCONTROLLED TOTAL-SYNTHESIS; FLUOROUS MIXTURE SYNTHESIS;

D O I：

10.1016/j.tet.2013.01.017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions, which permit the selective deprotection of one silyl-protected alcohol in the presence of another are reviewed. This review covers examples reported in the literature from mid-2004 through 2011. Examples are categorized by the type of silyl ether, that is, deprotected in the presence of the type of silyl ether that remains intact. A complete listing of examples is provided in tabular form at the end of the manuscript. © 2013 Elsevier Ltd. All rights reserved.

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页码：2383 / 2417

页数：35

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