Factors determining the formation of silver nanoparticles in the heterophase reduction OF Ag(I)

被引：2

作者：

Barna, A. V. ^{[1
]}

Lampeka, Ya D. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2012年 / 48卷 / 04期

关键词：

tetraamine complexes; copper; phosphomolybdate; redox reactions; nanoparticles; silver;

D O I：

10.1007/s11237-012-9267-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was shown that by varying the preparative conditions for the redox reactions between the phosphomolybdate complex of copper and an aqueous solution of silver(I) nitrate (the reaction time, the concentration of the metal salt, ultrasonic treatment) it is possible to control the content of the metal and the dispersion of its nanoparticles in composite materials containing silver nanoclusters and polyoxometalates.

引用

页码：240 / 245

页数：6

共 16 条

[1] EFFECT OF THE CHEMICAL NATURE OF POLYOXOMETALATE COMPLEXES ON REDOX PROCESSES LEADING TO THE FORMATION OF METALLIC SILVER NANOPARTICLES
Barna, A. V.
Lampeka, Ya. D.
[J]. THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2011, 47 (01) : 14 - 20
[2] Barna A. V., 2008, THESIS KYIV
[3] BARNA AV, 2007, THEOR EXP CHEM, V43, P316
[4] BARNA AV, 2007, THEOR EXP CHEM, V43, P119
[5] CRYSTAL-STRUCTURES OF ALPHA-[CO(II)W12O40]6- AND ITS HETEROPOLY BLUE 2E REDUCTION PRODUCT, ALPHA-[CO(II)W12O40]8- - STRUCTURAL, ELECTRONIC, AND CHEMICAL CONSEQUENCES OF ELECTRON DELOCALIZATION IN A MULTIATOM MIXED-VALENCE SYSTEM
CASANPASTOR, N
GOMEZROMERO, P
JAMESON, GB
BAKER, LCW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) : 5658 - 5663
[6] Polyoxometalate-based crystalline tubular microreactor: redox-active inorganic-organic hybrid materials producing gold nanoparticles and catalytic properties
Du, Dong-Ying
Qin, Jun-Sheng
Wang, Ting-Ting
Li, Shun-Li
Su, Zhong-Min
Shao, Kui-Zhan
Lan, Ya-Qian
Wang, Xin-Long
Wang, En-Bo
[J]. CHEMICAL SCIENCE, 2012, 3 (03) : 705 - 710
[7] Hill C.L., 2004, COMPREHENSIVE COORDI, V4, P679, DOI DOI 10.1016/B0-08-043748-6/03036-X
[8] Synthesis of remarkably stabilized metal nanostructures using polyoxometalates
Keita, Bineta
Liu, Tianbo
Nadjo, Louis
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (01) : 19 - 33
[9] HYDROTHERMAL SYNTHESIS AND STRUCTURE OF [H4ASIII2ASVMOV8MOVI4O40]-, A BICAPPED, REDUCED KEGGIN SPECIES
KHAN, MI
CHEN, Q
ZUBIETA, J
[J]. INORGANIC CHEMISTRY, 1993, 32 (13) : 2924 - 2928
[10] Liu R., 2011, J MATER CHEM, P14917

← 1 2 →