Capillary array electrophoresis for the research of asymmetric transformation reaction of L-proline to D-proline

被引：1

作者：

Wang, J ^{[1
]}

Liu, KY ^{[1
]}

Sun, GM ^{[1
]}

Bai, JL ^{[1
]}

Wang, L ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

来源：

JOURNAL OF SEPARATION SCIENCE | 2005年 / 28卷 / 18期

关键词：

asymmetric transformation; capillary array electrophoresis; enantiomeric excess; proline;

D O I：

10.1002/jssc.200500260

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

One asymmetric transformation reaction Of L-proline (L-Pro) to D-proline was studied by a home-made capillary array electrophoresis (CAE) for the first time. The aldehyde catalysts and the organic acid solvents for the asymmetric transformation reaction were rapidly screened and the enantiomeric excess values of the asymmetric product Of L-Pro were directly obtained from the electrophoretogram of CAE.

引用

页码：2551 / 2554

页数：4

共 19 条

[1]

Baumann M, 2001, ANGEW CHEM INT EDIT, V40, P4201, DOI 10.1002/1521-3773(20011119)40:22<4201::AID-ANIE4201>3.0.CO

[2]

2-V

[3] New catalysts and conditions for a C-H insertion reaction identified by high throughput catalyst screening [J].

Burgess, K ;

Lim, HJ ;

Porte, AM ;

Sulikowski, GA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (02) :220-222

[4] A chemosensor-based approach to catalyst discovery in solution and on solid support [J].

Copeland, GT ;

Miller, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) :4306-4307

[5]

Ding KL, 1999, ANGEW CHEM INT EDIT, V38, P497, DOI 10.1002/(SICI)1521-3773(19990215)38:4<497::AID-ANIE497>3.0.CO

[6]

2-G

[7] Miniaturization of enantioselectivce detectors [J].

Edkins, TJ ;

Bobbitt, DR .

ANALYTICAL CHEMISTRY, 2001, 73 (17) :488A-496A

[8] PROTOTROPIC ROUTES TO 1,3-DIPOLES AND 1,5-DIPOLES, AND 1,2-YLIDES - APPLICATIONS TO THE SYNTHESIS OF HETEROCYCLIC-COMPOUNDS [J].

GRIGG, R .

CHEMICAL SOCIETY REVIEWS, 1987, 16 (01) :89-121

[9]

Janes LE, 1998, CHEM-EUR J, V4, P2324, DOI 10.1002/(SICI)1521-3765(19981102)4:11<2324::AID-CHEM2324>3.3.CO

[10]

2-9

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