Peanut-Shell-like Porous Carbon from Nitrogen-Containing Poly-N-phenylethanolamine for High-Performance Supercapacitor

被引:63
作者
Wei, Xianjun [1 ]
Wan, Suige [1 ]
Jiang, Xiaoqiang [1 ]
Wang, Zhe [1 ]
Gao, Shuyan [1 ]
机构
[1] Henan Normal Univ, Sch Chem & Chem Engn, Minist Educ,Key Lab Green Chem Media & React, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Xinxiang 453007, Henan, Peoples R China
关键词
conducting polymer; nitrogen-doping; supercapacitor; energy density; power density; ELECTRODE MATERIALS; ACTIVATED CARBON; ENERGY-STORAGE; CO2; CAPTURE; ELECTROCHEMICAL PERFORMANCE; GRAPHITIC STRUCTURE; MESOPOROUS CARBONS; FUNCTIONAL-GROUPS; KOH ACTIVATION; IONIC LIQUIDS;
D O I
10.1021/acsami.5b05022
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
An efficient soft-template method is proposed for the synthesis of peanut shell-like porous carbon as high-performance supercapacitor electrode materials. The procedure is based on the pyrolysis and chemical activation processes using N-phenylethanolamine as precursor and KOH as activation agent. In a three-electrode system, the resultant carbon material has a specific capacitance of 356 F g(-1) A g(-1) a good stability over 1000 cycles. Besides, at a high current density of 30 A g(-1), it has a specific capacitance of 249 F g(-1) and maintains 96% after 10 000 cycles. In two-electrode cell configuration, it delivers about 21.53 Wh kg(-1) at a current density of 20 A g(-1), which is about 7 times higher than the commercial device (<3 WE kg(-1)). Both high specific capacitance and excellent cycling stabilities guarantee its utilization in supercapacitors.
引用
收藏
页码:22238 / 22245
页数:8
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