Photoionization of Cs (6p P-2(3/2)) atoms during the operation of a Cs D-2 line (852.1 nm: 6p P-2(3/2) -> 6s S-2(1/2)) laser, pumped by free -> free transitions of thermal Cs-Ar ground state pairs, has been investigated experimentally and computationally. Photoexcitation of Cs vapor/Ar mixtures through the blue satellite of the D-2 transition (peaking at 836.7 nm) selectively populates the P-2(3/2) upper laser level by the dissociation of the CsAr excited complex. Comparison of laser output energy data, for instantaneous pump powers up to 3MW, with the predictions of a numerical model sets an upper bound of 8 x 10(-26) cm(4) W-1 on the Cs (6p P-2(3/2)) two photon ionization cross-section at 836.7 nm which corresponds to a single photon cross-section of 2.4 x 10(-19) cm(2) for a peak pump intensity of 3MW cm(-2). (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4796040]