Transition metal catalyzed Glaser and Glaser-Hay coupling reactions: Scope, classical/green methodologies and synthetic applications

被引：41

作者：

Akhtar, Rabia ^{[1
]}

Zahoor, Ameer Fawad ^{[1
]}

机构：

[1] Govt Coll Univ Faisalabad, Dept Chem, Faisalabad 38000, Pakistan

来源：

SYNTHETIC COMMUNICATIONS | 2020年 / 50卷 / 22期

关键词：

Glaser cross coupling; macrocyclization; nanoparticles; palladium; silver; PSEUDO 5-COMPONENT SYNTHESIS; TERMINAL ALKYNES; HOMOCOUPLING REACTION; BINAPHTHYL POLYMERS; EFFICIENT SYNTHESIS; SONOGASHIRA; OPTIMIZATION; LIGAND; 1,3-BUTADIYNES; RADIAANNULENES;

D O I：

10.1080/00397911.2020.1802757

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Glaser coupling is one of the most important modern organic tool for the formation of carbon-carbon triple bond and has also been extensively used for the synthesis of polymers, macrocycles and oligomers (known for their electrochemical, optical and electronic properties). Although this reaction is generally catalyzed by copper complexes yet recent advances including new ligands, additives and silver/cobalt/palladium catalysts make this coupling reaction more effective. This review highlights the role of various catalytic systems used in Glaser- and Glaser-Hay coupling reactions for the production of a variety of C-C triple bonds with wide structural features.

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收藏

页码：3337 / 3368

页数：32

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