Fabrication of PMMA-SiO2Transparent Nanocomposite Films as Energy Storage Barriers

被引:3
作者
Dastyar, Y. [1 ]
Zerafat, M. M. [1 ]
Jamekhorshid, A. [2 ]
机构
[1] Shiraz Univ, Fac Adv Technol, Nanochem Engn Dept, Shiraz, Iran
[2] Persian Gulf Univ, Fac Petr Gas & Petrochem Engn, Bushehr 75169, Iran
关键词
Phase change materials; Poly (methyl methacrylate); Nanocomposite; Sodium sulfate; Thermal energy storage; PHASE-CHANGE MATERIALS; CHANGE MATERIAL PCM; COMPOSITE; ACID;
D O I
10.1007/s10904-020-01736-x
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the present study, sol-gel synthesized silica shell is selected to encapsulate Na2SO4 center dot 10H(2)O as the phase change agent with a 30 degrees C phase change temperature. In the next step, the produced nanocomposites are dispersed in poly (methyl methacrylate) (PMMA) as a transparent polymer to produce films that can be considered as an alternative for transparent barriers like glass windows. Thermal analysis indicates that the synthesized nanocomposites show an efficient thermal energy storage capacity, which is also preserved through several thermal cycles. Based on the results, the as-prepared phase change material with a 40% encapsulation ratio and 96.29 J/g and 83.03 heating and cooling enthalpies and 32 degrees C and 10 degrees C phase change temperatures for heating and cooling, respectively and also no phase separation can be considered as a promising material for inclusion in transparent polymeric matrices as an alternative for glass windows.
引用
收藏
页码:599 / 613
页数:15
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