A new equivalent of the CF3S(O)+ cation.: Synthesis of trifluoromethanesulfinates and trifluoromethanesulfinamides.

被引：49

作者：

Billard, T

Greiner, A

Langlois, BR

机构：

[1] Univ Lyon 1, UMR CNRS 5622, Equipe Fluor, F-69622 Villeurbanne, France

[2] Rhone Poulenc, Direct Sci, F-69192 St Fons, France

来源：

TETRAHEDRON | 1999年 / 55卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(99)00364-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The solution of sodium trifluoromethanesulfinate (sodium "triflinate") and phospholyl chloride (2/1), in AcOEt, behaves like an equivalent of the CF3S(O)(+) cation. It can be used in situ to prepare trifluoromethanesulfinates (CF3S(O)OR) or trifluoromethanesulfinamides (CF3S(O)NHR) at room temperature from alcohols or amines, respectively, (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：7243 / 7250

页数：8

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