Rhodium-catalyzed Decarbonylation of Acylsilanes

被引：9

作者：

Yoshida, Tomoki ^{[1
]}

Kodama, Takuya ^{[1
,2
]}

Tobisu, Mamoru ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 12期

关键词：

Acylsilanes; Decarbonylation; Homogeneous catalysis; Organosilicon compounds; Rhodium catalyst; NOBLE-METAL COMPOUNDS; ORGANIC SYNTHESES; DIARYL KETONES; COMPLEXES; CLEAVAGE; PALLADIUM; ESTERS; THIOETHERIFICATION; ACTIVATION; MECHANISM;

D O I：

10.1002/ajoc.202200610

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium-catalyzed decarbonylation of acylsilanes is reported. This reaction proceeds through the cleavage of a carbon-silicon bond in acylsilanes. When two different acylsilanes are reacted in one batch, crossover products are formed. These results indicate that two mechanisms are operating in this catalytic reaction.

引用

页数：4

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