Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

被引：100

作者：

Filippou, Alexander C. ^{[1
]}

Lebedev, Yury N. ^{[1
]}

Chernov, Oleg ^{[1
]}

Strassmann, Martin ^{[1
]}

Schnakenburg, Gregor ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 27期

关键词：

ionic compounds; low-valent compounds; N-heterocyclic carbenes; silicon; silyliumylidenes; MOLECULAR-STRUCTURE; COUPLING-CONSTANTS; COMPOUND; ADDUCTS; SILENES; VALUES; MODEL;

D O I：

10.1002/anie.201301363

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand swap: The exchange of N-heterocyclic carbene (NHC) ligands at SiII centers is shown to provide access to a dicationic NHC complex of silicon(II), and an NHC adduct of the iodosilyliumylidene cation SiI +, [SiI(IiPr2Me2)(IDipp)]+ (see picture). Characterization studies led to the discovery of an unprecedented C-H×××Si anagostic interaction for [SiI(IiPr 2Me2)(IDipp)]+. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6974 / 6978

页数：5

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