Synthesis of a polyphenylene-co-furan and polyphenylene-co-thiophene and comparison of their electroluminescent properties

被引：70
作者：
Saadeh, H
Goodson, T
Yu, LP
机构：
[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637
[2] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637
来源：
MACROMOLECULES | 1997年 / 30卷 / 16期
关键词：
D O I：
10.1021/ma970577+
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new polyphenylene-co-furan (PPF) and a polyhenylene-co-thiophene (PPT) have been synthesized utilizing the Stille coupling reaction and their luminescence properties characterized. The UV-vis, electroluminescence (EL), photoluminescence (PL), and current-field II-Fl characteristics, as well as the stability of the emission of light, were studied in detail for both polymer LED devices. Comparisons of the EL and PL characteristics between PPT and PPF suggest that the quantum efficiency of PPF is higher than that of PPT. However, it was also found that PPF is photochemically unstable and its electroluminescent intensity decays faster than that of PPT.
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页码：4608 / 4612
页数：5
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