Solubility of C. I. Disperse Red 60 and C. I. Disperse Blue 60 in supercritical carbon dioxide

被引:165
作者
Sung, HD [1 ]
Shim, JJ [1 ]
机构
[1] Yeungnam Univ, Sch Chem Engn & Technol, Kyongsan 712749, Kyongbuk, South Korea
关键词
D O I
10.1021/je990018t
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility of two disperse dyes (C. I. Disperse Red 60 and C. I. Disperse Blue 60) in supercritical carbon dioxide was measured at pressures up to 35 MPa and temperatures between 313 K and 423 K in a closed-loop equilibrium apparatus equipped with a magnetic pump. The solubility increased with pressure at the same temperature. Solubility isotherms were straight and parallel to each other when the logarithm of solubility was plotted versus density of the fluid, whereas the slope of each isotherm decreased with increasing temperature when it was plotted versus the logarithm of density. The experimental data were successfully correlated using two semiempirical equations.
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页码:985 / 989
页数:5
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