Synthesized of nanophotocatalyst ZnO and ZnO doped with SnO2 and their application photochemical degradation a surfactant in aqueous solutions

被引:4
作者
Akhgar, M. [1 ]
Giahi, M. [1 ]
机构
[1] Islamic Azad Univ, Lahijan Branch, Dept Chem, Lahijan, Iran
关键词
CI-ACID YELLOW-23; PHOTOCATALYTIC DEGRADATION; NANOPARTICLES; ENVIRONMENT; PHARMACEUTICALS; DRUGS; DYES;
D O I
10.1134/S1070427215060142
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, we synthesized of pure ZnO and ZnO doped with SnO2 nanophotocatalyst by sol gel method. The successful synthesis of ZnO nanopowders was evident by XRD lines. Furthermore SnO2 were well incorporated into the ZnO crystal lattice in doped sample. Scanning electron microscope (SEM) analysis revealed that the SnO2 were well incorporated into the ZnO crystal lattice. The photocatalytic activities of these materials were investigated for Sodium alkyl benzene sulfonate removal from aqueous solution under UV light irradiation. It was shown that the use of ZnO/SnO2 as photocatalyst have better photocatalytic activity for degradation of Sodium alkyl benzene sulfonate than ZnO. The effects of initial concentration of surfactant, catalyst loading, pH, addition of oxidant on the reaction rate were ascertained and optimum conditions for maximum degradation was determined.
引用
收藏
页码:985 / 989
页数:5
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共 21 条
[1]   Kinetic study on photocatalytic degradation of CI Acid Yellow 23 by ZnO photocatalyst [J].
Behnajady, M. A. ;
Modirshahla, N. ;
Hamzavi, R. .
JOURNAL OF HAZARDOUS MATERIALS, 2006, 133 (1-3) :226-232
[2]   Strategic survey of therapeutic drugs in the rivers Po and Lambro in northern Italy [J].
Calamari, D ;
Zuccato, E ;
Castiglioni, S ;
Bagnati, R ;
Fanelli, R .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (07) :1241-1248
[3]   Photocatalytic degradation of CI Acid Orange 52 in the presence of Zn-doped TiO2 prepared by a stearic acid gel method [J].
Chen, Cheng ;
Wang, Zhuyi ;
Ruan, Shengping ;
Zou, Bo ;
Zhao, Meng ;
Wu, Fengqing .
DYES AND PIGMENTS, 2008, 77 (01) :204-209
[4]   Decolorization of CI Acid Yellow 23 solution by electrocoagulation process: Investigation of operational parameters and evaluation of specific electrical energy consumption (SEEC) [J].
Daneshvar, N. ;
Khataee, A. R. ;
Ghadim, A. R. Amani ;
Rasoulifard, M. H. .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 148 (03) :566-572
[5]   Pharmaceuticals and personal care products in the environment: Agents of subtle change? [J].
Daughton, CG ;
Ternes, TA .
ENVIRONMENTAL HEALTH PERSPECTIVES, 1999, 107 :907-938
[6]   Partial oxidation of methanol for hydrogen production over carbon nanotubes supported Cu-Zn catalysts [J].
Eswaramoorthi, I. ;
Sundaramurthy, V. ;
Dalai, A. K. .
APPLIED CATALYSIS A-GENERAL, 2006, 313 (01) :22-34
[7]   SnO2 doped ZnO nanostructures for highly efficient photocatalyst [J].
Faisal, M. ;
Ibrahim, Ahmed A. ;
Harraz, Farid A. ;
Bouzid, Houcine ;
Al-Assiri, M. S. ;
Ismail, Adel A. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 397 :19-25
[8]   Synthesis of CuO/ZnO Nanoparticles and Their Application for Photocatalytic Degradation of Lidocaine HCl by the Trial-and-error and Taguchi Methods [J].
Giahi, M. ;
Badalpoor, N. ;
Habibi, S. ;
Taghavi, H. .
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (07) :2176-2182
[9]   Photocatalytic degradation of betamethasone sodium phosphate in aqueous solution using ZnO nanopowder [J].
Giahi, M. ;
Taghavi, H. ;
Habibi, S. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (13) :2003-2007
[10]   Occurrence, fate and effects of pharmaceutical substances in the environment - A review [J].
Halling-Sorensen, B ;
Nielsen, SN ;
Lanzky, PF ;
Ingerslev, F ;
Lutzhoft, HCH ;
Jorgensen, SE .
CHEMOSPHERE, 1998, 36 (02) :357-394