Conversion of Xylose Solution into Furfural at Atmospheric Pressure over the Solid Acid

被引:0
作者
Wang, Yuankui [1 ]
Jia, Huizhen [1 ]
Li, Yunzheng [1 ]
Zhang, Qingshan [1 ]
Yin, Hongquan [1 ]
机构
[1] Beijing Inst Technol, Beijing 100081, Peoples R China
来源
PROCEEDINGS OF THE 2015 INTERNATIONAL CONFERENCE ON MATERIALS, ENVIRONMENTAL AND BIOLOGICAL ENGINEERING | 2015年 / 10卷
关键词
Furfural; Xylose; Solid acid; Solvent extraction; Atmospheric pressure; CATALYSTS;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study mainly focused on the dehydration of xylose to furfural with green catalysis. The reaction was under atmospheric pressure, with the SO42-/ZrO2 as the catalyst plus an inorganic salt (NaCl) as promoter. DMSO was used as a renewable extraction solvent in a biphasic system. The optimal catalytic reaction conditions were determined by single factor design. The results showed that the optimal catalytic reaction conditions were the following conditions: 30 mL of DMSO and 2g xylose, 1 g NaCl, 2.5g SO42-/ZrO2 and heating for 4 h. It resulted in the maximum yield of 47.7 %. The experimental results showed that the preparation of furfural from xylose solution system with the solid acid catalyst, has the huge development potential. The addition of an inorganic salt (NaCl) to the aqueous phase was shown to improve the yield of furfural.
引用
收藏
页码:488 / 491
页数:4
相关论文
共 6 条
[1]   New colored compounds from the Maillard reaction between xylose and lysine [J].
Arnoldi, A ;
Corain, EA ;
Scaglioni, L ;
Ames, JM .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (03) :650-655
[2]   Modified versions of sulfated zirconia as catalysts for the conversion of xylose to furfural [J].
Dias, Ana S. ;
Lima, Sergio ;
Pillinger, Martyn ;
Valente, Anabela A. .
CATALYSIS LETTERS, 2007, 114 (3-4) :151-160
[3]   Furfural: Hemicellulose/xylosederived biochemical [J].
Mamman, Ajit Singh ;
Lee, Jong-Min ;
Kim, Yeong-Cheol ;
Hwang, In Taek ;
Park, No-Joong ;
Hwang, Young Kyu ;
Chang, Jong-San ;
Hwang, Jin-Soo .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2008, 2 (05) :438-454
[4]   Selective preparation of furfural from xylose over microporous solid acid catalysts [J].
Moreau, C ;
Durand, R ;
Peyron, D ;
Duhamet, J ;
Rivalier, P .
INDUSTRIAL CROPS AND PRODUCTS, 1998, 7 (2-3) :95-99
[5]   Production of furfural from xylose at atmospheric pressure by dilute sulfuric acid and inorganic salts [J].
Rong, Chunguang ;
Ding, Xuefeng ;
Zhu, Yanchao ;
Li, Ying ;
Wang, Lili ;
Qu, Yuning ;
Ma, Xiaoyu ;
Wang, Zichen .
CARBOHYDRATE RESEARCH, 2012, 350 :77-80
[6]   Conversion of D-xylose into furfural with mesoporous molecular sieve MCM-41 as catalyst and butanol as the extraction phase [J].
Zhang, Junhua ;
Zhuang, Junping ;
Lin, Lu ;
Liu, Shijie ;
Zhang, Zhuo .
BIOMASS & BIOENERGY, 2012, 39 :73-77