A comparative study of poly(acrylic acid) and poly(styrenesulfonic acid) doped into polyaniline as platinum catalyst support for methanol electro-oxidation

被引：27

作者：

Kuo, Chung-Wen ^{[2
]}

Chen, Bor-Kuan ^{[3
]}

Tseng, Yu-Hsi ^{[2
]}

Hsieh, Tar-Hwa ^{[2
]}

Ho, Ko-Shan ^{[2
]}

Wu, Tzi-Yi ^{[1
]}

Chen, Ho-Rei ^{[2
]}

机构：

[1] Natl Yunlin Univ Sci & Technol, Dept Chem Engn & Mat Engn, Yunlin 64002, Taiwan

[2] Natl Kaohsiung Univ Appl Sci, Dept Chem & Mat Engn, Kaohsiung 80778, Taiwan

[3] Kun Shan Univ, Dept Mat Engn, Tainan 71003, Taiwan

来源：

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS | 2012年 / 43卷 / 05期

关键词：

Polyaniline; Poly(acrylic acid); Poly(styrenesulfonic acid); Nanowires; Cyclic voltammetry; Methanol oxidation; FORMIC-ACID; FUEL-CELLS; ELECTROCATALYTIC ACTIVITY; COMPOSITE FILMS; SULFONIC-ACID; PT-RU; OXIDATION; ELECTRODES; PARTICLES; NANOWIRES;

D O I：

10.1016/j.jtice.2012.03.008

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Polyaniline (PANI) is doped with poly(acrylic acid) (PAA) and poly(styrenesulfonic acid) (PSS) via a doping-dedoping-redoping process. Fourier transform infrared (FT-IR) spectroscopy results confirm that PANI is doped with PSS (or PAA). X-ray photoelectron spectroscopy (XPS) results indicate that the nitrogen atoms of PANI-PSS are more positively charged than those of PANI-PAA. Scanning electron microscopy (SEM) images reveal that PANI-PSS is composed of highly porous nanowires. Platinum (Pt) can be deposited onto PANI-PAA and PANI-PSS films using the potentiostatic mode to obtain PANI-PAA-Pt and PANI-PSS-Pt composite electrodes, respectively. Auger electron spectroscopy (AES) results indicate that Pt particles disperse more uniformly into the spatial regions of PANI-PSS than those of PANI-PAA. The SO3H group in PANI-PSS may facilitate the electrodeposition of Pt better than the CO2H group in PANI-PAA. Cyclic voltammetry results and chronoamperometric response measurements show that the activity and stability toward methanol oxidation of the PANI-PSS-Pt electrode are better than those of the PANI-PAA-Pt electrode. (C) 2012 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.

引用

页码：798 / 805

页数：8

共 46 条

[11] Platinum-modified polyaniline/polysulfone composite film electrodes and their electrocatalytic activity for methanol oxidation [J].

Hu, Z. A. ;

Ren, L. J. ;

Feng, X. J. ;

Wang, Y. P. ;

Yang, Y. Y. ;

Shi, J. ;

Mo, L. P. ;

Lei, Z. Q. .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (01) :97-102

[12] Spatially electrodeposited platinum in polyaniline doped with poly(styrene sulfonic acid) for methanol oxidation [J].

Huang, Li-Ming ;

Tang, Wang-Rung ;

Wen, Ten-Chin .

JOURNAL OF POWER SOURCES, 2007, 164 (02) :519-526

[13] Preparation and properties of sulfonated poly(ether ether ketone)/Analcime composite membrane for a proton exchange membrane fuel cell (PEMFC) [J].

Intaraprasit, Nuannid ;

Kongkachuichay, Paisan .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2011, 42 (01) :190-195

[14] Progress in non-precious metal oxide-based cathode for polymer electrolyte fuel cells [J].

Ishihara, Akimitsu ;

Ohgi, Yoshiro ;

Matsuzawa, Koichi ;

Mitsushima, Shigenori ;

Ota, Ken-ichiro .

ELECTROCHIMICA ACTA, 2010, 55 (27) :8005-8012

[15] Current distribution and cathode flooding prediction in a PEM fuel cell [J].

Jamekhorshid, A. ;

Karimi, G. ;

Noshadi, I. .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2011, 42 (04) :622-631

[16] The effect of different valency cations on DMFC performance [J].

Jie, Xiao ;

Shao, Zhi-Gang ;

Yi, Baolian .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (05) :700-702

[17] Preparation process for improving cathode electrode structure in direct methanol fuel cell [J].

Jung, Namgee ;

Cho, Yoon-Hwan ;

Choi, Kwang-Hyun ;

Lim, Ju Wan ;

Cho, Yong-Hun ;

Ahn, Minjeh ;

Kang, Yun Sik ;

Sung, Yung-Eun .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (06) :754-757

[18] ELECTROOXIDATION OF FORMIC-ACID AT A PLATINUM-ELECTRODE MODIFIED WITH ANILINE OR POLYANILINE [J].

KAZARINOV, VE ;

ANDREEV, VN ;

SPITSYN, MA ;

MAYOROV, AP .

ELECTROCHIMICA ACTA, 1990, 35 (09) :1459-1463

[19] Electroactivity of Pt-Ru/polyaniline composite catalyst-electrodes prepared by electrochemical deposition methods [J].

Kim, Seok ;

Park, Soo-Jin .

SOLID STATE IONICS, 2008, 178 (37-38) :1915-1921

[20] Electrospun bimetallic nanowires of PtRh and PtRu with compositional variation for methanol electrooxidation [J].

Kim, Yong Seok ;

Nam, Sang Hoon ;

Shim, Hee-Sang ;

Ahn, Hyo-Jin ;

Anand, Manish ;

Kim, Won Bae .

ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (07) :1016-1019

← 1 2 3 4 5 →