Synthesis of [2]Catenanes by Template-Directed Clipping Approach

被引：19

作者：

Li, Ziyong ^{[1
]}

Liu, Wenju ^{[1
]}

Wu, Jishan ^{[2
]}

Liu, Sheng Hua ^{[1
]}

Yin, Jun ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 16期

基金：

中国国家自然科学基金;

关键词：

THERMODYNAMIC CONTROL; CATENANES; COMPLEXES; ROTAXANES; MACROCYCLE;

D O I：

10.1021/jo3012804

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of [2]catenanes were efficiently synthesized in high yields by a template-directed clipping approach with the formation of one macrocycle around another macrocycle containing a dialkylammonium recognition site. Their structures were identified by the NMR spectra and ESI mass spectrometry, and their geometries were investigated by the theoretical calculation.

引用

页码：7129 / 7135

页数：7

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