A vanadium(IV) pyrazolate metal-organic polyhedron with permanent porosity and adsorption selectivity

被引：36

作者：

Augustyniak, A. W. ^{[1
]}

Fandzloch, M. ^{[2
]}

Domingo, M. ^{[3
]}

Lakomska, I. ^{[2
]}

Navarro, J. A. R. ^{[3
]}

机构：

[1] Inst Publ Hlth & Environm Protect, PL-02835 Warsaw, Poland

[2] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland

[3] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 79期

关键词：

MAGNETIC-PROPERTIES; FRAMEWORKS; COMPLEXES; LIGAND; CLUSTERS; TRANSITION; REACTIVITY; CATALYSTS; POLYMERS;

D O I：

10.1039/c5cc05913e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A vanadium(IV) pyrazolate-based open metal-organic polyhedron of [V-3(mu(3)-O)O(OH)(2)(mu(4)-BPD)(1.5)(mu-HCOO)(3)] (BDP = benzene-1,4-bipyrazolate) formulation gives rise to a porous crystal structure exhibiting micro and mesoporosity which is useful for selective adsorption of gases.

引用

页码：14724 / 14727

页数：4

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